Kinetic Model of Crude Palm Oil Hydrocracking Over Ni/Mo ZrO2–Pillared Bentonite Catalyst

  • Hasanudin Hasanudin Department of Chemistry, Faculty of Mathematic and Natural Science, Universitas Sriwijaya, Palembang, Sumatera Selatan 30662, Indonesia
  • Addy Rachmat Department of Chemistry, Faculty of Mathematic and Natural Science, Universitas Sriwijaya, Palembang, Sumatera Selatan 30662, Indonesia
  • Muhammad Said Department of Chemistry, Faculty of Mathematic and Natural Science, Universitas Sriwijaya, Palembang, Sumatera Selatan 30662, Indonesia
  • Karna Wijaya Department of Chemistry, Faculty of Mathematic and Natural Science, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia

Abstract

Crude Palm Oil hydrocrcaking has been carried out over Ni/Mo ZrO2–pillared bentonite catalyst in a fixed bed reactor. Crude Palm Oil hydrocracking over Ni/Mo ZrO2–pillared bentonite catalyst formed 3 products i.e. gas, oil and coke. The oil product from Crude Palm Oil hydrocracking was analyzed by using gas chromatography to determine its composition. Three types of fraction were classified i.e. gasoline, kerosene and diesel oil. In this research, the focused of the study is of hydrocracking kinetics by using lump kinetic models. The kinetic model was solved by using the software MATLAB R2018b involves the effect of catalyst activity on the reaction rate. The results of the kinetic study show that the 4-lump (Crude Palm Oil, gas coke and oil) and 6-lump reaction models (Crude Palm Oil, gas, coke, gasoline, kerosene and diesel) can be used to explain the Crude Palm Oil hydrocracking over Ni/Mo ZrO2–pillared bentonite catalyst. The 4-lump kinetic model has 5 rate constants and the 6-lump kinetic model has 14 rate constants.

Keywords: pillared bentonite, catalytic activity, lump reaction kinetic, hydrocracking
Published online
2019-12-17
How to Cite
[1]
Hasanudin, H., Rachmat, A., Said, M. and Wijaya, K. (2020). Kinetic Model of Crude Palm Oil Hydrocracking Over Ni/Mo ZrO2–Pillared Bentonite Catalyst. Periodica Polytechnica Chemical Engineering. 64, 2 (2020), 238-247. https://doi.org/10.3311/PPch.14765.
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Articles