DIE MASSENSPEKTROMETRISCHE UNTERSUCHUNG DER IM RING SUBSTITUIERTEN SILATRANE

Authors

  • Pál Hencsei
  • Ilona Kovács
  • László Bihátsi
  • Éva B. Karsai
  • Tibor Müller
  • Péter Miklós

Abstract

The aim of this work was to investigate the mass-spectrometric properties of in ring substituted silatranes. We found that in trimethylsilatranes the [M-R]+ ion (m/z = 216) is the basispeak. In silatranones the CO2 fragment leaves first and the basispeak is the [M-CO2]+ ion. In carba-silatranes we found two basic procedures depending on R. In some cases the basispeak is the [M-R] + ion, but sometimes one of the rings opens and the basispeak is the [M-C2H5]+ ion.

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How to Cite

Hencsei, P., Kovács, I., Bihátsi , L., B. Karsai, É., Müller, T., Miklós, P. “DIE MASSENSPEKTROMETRISCHE UNTERSUCHUNG DER IM RING SUBSTITUIERTEN SILATRANE ”, Periodica Polytechnica Chemical Engineering, 33(1), pp. 3–9, 1989.

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