Adsorption Properties of Copper (II) Ion From Aqueous Solution by Starch-Grafted Polyacrylamide and Crosslinked Starch-Grafted Polyacrylamide

Authors

  • Jun Tan
    Affiliation

    College of Biological and Chemical Engineering, Jiaxing University

  • Xiaoyan Wei
    Affiliation

    College of Biological and Chemical Engineering of Jiaxing University, Jiaxing

  • Yuxia Ouyang
  • Juhong Fan
  • Rui Liu
https://doi.org/10.3311/PPch.7185

Abstract

Starch-grafted polyacrylamide (SA) and cross-linked starch-grafted polyacrylamide (CSA) had been synthesized via grafting polymerization from corn starch and used as adsorbents for the removal of Cu(II) ion from aqueous solution. The equilibrium, kinetics and thermodynamics of adsorption processes of SA and CSA were investigated and compared. It was found that the adsorption capacity of Cu(II) of SA and CSA could reach the maximum within 60 min when the pH was 6. The adsorption kinetics of CSA and SA for Cu(II) was favorably described by the pseudo-second-order kinetic model and the adsorption isotherm was described well with the Freundlich isotherm model. Thermodynamic studies indicated that the adsorption was a spontaneous and endothermic process with increased entropy, and the rise of temperature would benefit the adsorption; the enthalpy change(ΔH), the entropy change (ΔS) and free energy change (ΔG) of the adsorption process of Cu(II) on SA and CSA were calculated with adsorption isotherm data and basic thermodynamic relations.

Keywords:

Adsorption, Copper ion(II), Starch-grafted polyacrylamide, Cross-linked starch-grafted polyacrylamide, Kinetics, Thermodynamics

Published Online

2014-07-31

How to Cite

Tan, J., Wei, X., Ouyang, Y., Fan, J., Liu, R. “Adsorption Properties of Copper (II) Ion From Aqueous Solution by Starch-Grafted Polyacrylamide and Crosslinked Starch-Grafted Polyacrylamide”, Periodica Polytechnica Chemical Engineering, 58(2), pp. 131–139, 2014. https://doi.org/10.3311/PPch.7185

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Section

Articles