Bipolar Packed-bed Electrochemical Reactor for the Degradation of Diclofenac; a Bio-refractory Organic Compound

  • Carlos Carlesi Escuela de Ingeniería Química, Pontificia Universidad Católica de Valparaíso, Chile
  • Nadia Guajardo Centro de Desarrollo y Transferencia Tecnológica (CEDYTEC), Facultad de Ingeniería, Ciencia y Tecnología, Universidad Bernardo O’Higgins, Chile
  • Alessandro Monteverde Videla Department of Applied Science and Technology, Politecnico di Torino, Italy
  • Jaime Morales Escuela de Ingeniería Química, Pontificia Universidad Católica de Valparaíso, Chile
  • Álvaro Aracena Escuela de Ingeniería Química, Pontificia Universidad Católica de Valparaíso, Chile

Abstract

Pharmaceuticals have low biodegradability and can retain their chemical structure for long periods of time leading to an accumulation in the environment causing irreversible changes. Electrochemical oxidation has been proved to be an environmentally friendly and economically viable solution for bio-refractory of organic molecules as well as for the disinfection of wastewaters. This paper aims to evaluate the performance of specific energy consumption for a given reduction of toxic organic compound loads in a continuous flow bipolar packed-bed electrochemical reactor and compare this with a classical parallel plate reactor. The energy cost for both the parallel plate and bipolar electrochemical reactors are similar (around 1.6 kWh m-3) lower than other advanced oxidation process reported in literature. However, the bipolar configuration is particularly suitable for low conductivity waste water and/or for avoiding the formation of organochloride compounds in a chloride rich wastewater.

Keywords

electroxidation, advanced oxidation process, tin oxide electrode, pharmaceutical compounds, bipolar electrochemical reactor, Diclofenac
Published
18-08-2017
How to Cite
CARLESI, Carlos et al. Bipolar Packed-bed Electrochemical Reactor for the Degradation of Diclofenac; a Bio-refractory Organic Compound. Periodica Polytechnica Chemical Engineering, [S.l.], aug. 2017. ISSN 1587-3765. Available at: <https://pp.bme.hu/ch/article/view/10354>. Date accessed: 26 sep. 2017. doi: https://doi.org/10.3311/PPch.10354.
Section
Articles